The historic Distillery District is home to Segway of Ontario where you can take guided tours of the revitalized Victorian industrial area on the two wheeled vehicles.
The Segway really did not catch on for general use for a variety of reasons such as riding restrictions (can't go on sidewalk, can't go on the road) and cost ($5,000 plus) so if you want to see or ride a Segway you need to come down to the Distillery District.
